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The stratosphere (/
Ozone and temperatureEdit
The mechanism describing the formation of the ozone layer was described by British mathematician Sydney Chapman in 1930. Molecular oxygen absorbs high energy sunlight in the UV-C region, at wavelengths shorter than about 240 nm. Radicals produced from the homolytically split oxygen molecules combine with molecular oxygen to form ozone. Ozone in turn is photolysed much more rapidly than molecular oxygen as it has a stronger absorption that occurs at longer wavelengths, where the solar emission is more intense. Ozone (O3) photolysis produces O and O2. The oxygen atom product combines with atmospheric molecular oxygen to reform O3, releasing heat. The rapid photolysis and reformation of ozone heats the stratosphere resulting in a temperature inversion. This increase of temperature with altitude is characteristic of the stratosphere; its resistance to vertical mixing means that it is stratified. Within the stratosphere temperatures increase with altitude (see temperature inversion); the top of the stratosphere has a temperature of about 270 K (−3°C or 26.6°F). This vertical stratification, with warmer layers above and cooler layers below, makes the stratosphere dynamically stable: there is no regular convection and associated turbulence in this part of the atmosphere. However, exceptionally energetic convection processes, such as volcanic eruption columns and overshooting tops in severe supercell thunderstorms, may carry convection into the stratosphere on a very local and temporary basis. Overall the attenuation of solar UV at wavelengths that damage DNA by the ozone layer allows life to exist on the surface of the planet outside of the ocean. All air entering the stratosphere must pass through the tropopause, the temperature minimum that divides the troposphere and stratosphere. The rising air is literally freeze dried; the stratosphere is a very dry place. The top of the stratosphere is called the stratopause, above which the temperature decreases with height.
Sydney Chapman gave a correct description of the source of stratospheric ozone and its ability to generate heat within the stratosphere; he also wrote that ozone may be destroyed by reacting with atomic oxygen, making two molecules of molecular oxygen. We now know that there are additional ozone loss mechanisms, and that these mechanisms are catalytic meaning that a small amount of the catalyst can destroy a great number of ozone molecules. The first is due to the reaction of hydroxyl radicals OH· with ozone. OH is formed by the reaction of electronically excited oxygen atoms produced by ozone photolysis, with water vapor. While the stratosphere is dry, additional water vapor is produced in situ by the photochemical oxidation of methane (CH4). The HO2 radical produced by the reaction of OH with O3 is recycled to OH by reaction with oxygen atoms or ozone. In addition, solar proton events can significantly affect ozone levels via radiolysis with the subsequent formation of OH . Laughing gas or nitrous oxide (N2O) is produced by biological activity at the surface and is oxidised to NO in the stratosphere; the so-called NOx radical cycles also deplete stratospheric ozone. Finally, chlorofluorocarbon molecules are photolysed in the stratosphere releasing chlorine atoms that react with ozone giving ClO and O2. The chlorine atoms are recycled when ClO reacts with O in the upper stratosphere, or when ClO reacts with itself in the chemistry of the Antarctic ozone hole.
Paul J. Crutzen, Mario J. Molina and F. Sherwood Rowland were awarded the Nobel Prize in Chemistry in 1995 for their work describing the formation and decomposition of stratospheric ozone.
Commercial airliners typically cruise at altitudes of 9–12 km (30,000–39,000 ft) which is in the lower reaches of the stratosphere in temperate latitudes. This optimizes fuel efficiency, mostly due to the low temperatures encountered near the tropopause and low air density, reducing parasitic drag on the airframe. Stated another way, it allows the airliner to fly faster while maintaining lift equal to the weight of the plane. (The fuel consumption depends on the drag, which is related to the lift by the lift-to-drag ratio.) It also allows the airplane to stay above the turbulent weather of the troposphere.
Because the temperature in the tropopause and lower stratosphere is largely constant with increasing altitude, very little convection and its resultant turbulence occurs there. Most turbulence at this altitude is caused by variations in the jet stream and other local wind shears, although areas of significant convective activity (thunderstorms) in the troposphere below may produce turbulence as a result of convective overshoot.
On October 24, 2014, Alan Eustace became the record holder for reaching the altitude record for a manned balloon at 135,890 ft (41,419 m). Dr Eustace also broke the world records for vertical speed skydiving, reached with a peak velocity of 1,321 km/h (822 mph) and total freefall distance of 123,414 ft (37,617 m) – lasting four minutes and 27 seconds.
Circulation and mixingEdit
The stratosphere is a region of intense interactions among radiative, dynamical, and chemical processes, in which the horizontal mixing of gaseous components proceeds much more rapidly than does vertical mixing. The overall circulation of the stratosphere is termed as Brewer-Dobson circulation, which is a single celled circulation, spanning from the tropics up to the poles, consisting of the tropical upwelling of air from the tropical troposphere and the extra-tropical downwelling of air. Stratospheric Circulation is a pre-dominantly wave-driven circulation in that the tropical upwelling is induced by the wave force by the westward propagating Rossby Waves, in a phenomenon called Rossby-Wave pumping.
An interesting feature of stratospheric circulation is the QBO in the tropical latitudes, which is driven by gravity waves that are convectively generated in the troposphere. The QBO induces a secondary circulation that is important for the global stratospheric transport of tracers, such as ozone or water vapor.
Another large-scale feature that significantly influences Stratospheric Circulation is the breaking planetary waves resulting in intense quasi-horizontal mixing in the midlatitudes. This breaking is much more pronounced in the winter hemisphere where this region is called the surf zone. This breaking is caused due to a highly non-linear interaction between the vertically propagating planetary waves and the isolated high potential vorticity region known as Polar Vortex. The resultant breaking causes large scale mixing of air and other trace gases throughout the midlatitude surf zone. The timescale of this rapid mixing is much smaller than the much slower timescales of upwelling in the tropics and downwelling in the extratropics.
During northern hemispheric winters, sudden stratospheric warmings, caused by the absorption of Rossby waves in the stratosphere, can be observed in approximately half of winters when easterly winds develop in the stratosphere. These events often precede unusual winter weather  and may even be responsible for the cold European winters of the 1960s.
Stratospheric warming of the polar vortex results in its weakening. When the vortex is strong, it keeps the cold, high pressure air masses contained in the arctic; when the vortex weakens, air masses move equatorward, and results in rapid changes of weather in the mid latitudes.
Bacterial life survives in the stratosphere, making it a part of the biosphere. In 2001, dust was collected at a height of 41 kilometres in a high-altitude balloon experiment and was found to contain bacterial material when examined later in the laboratory.
Some bird species have been reported to fly at the upper levels of the troposphere . On November 29, 1973, a Rüppell's vulture (Gyps rueppelli) was ingested into a jet engine 11,278 m (37,000 ft) above the Ivory Coast, and bar-headed geese (Anser indicus) reportedly overfly Mount Everest's summit, which is 8,848 m (29,029 ft).
In 1902, Léon Teisserenc de Bort from France and Richard Assmann from Germany, in separate but coordinated publications and following years of observations, published the discovery of an isothermal layer at around 11–14 km, which is the base of the lower stratosphere. This was based on temperature profiles from mostly unmanned and a few manned instrumented balloons.
- "ISS022-E-062672 caption". NASA. Archived from the original on 19 November 2012. Retrieved 21 September 2012.
- "Atmospheric Temperature Trends, 1979–2005". NASA/Earth Observatory. 6 July 2007. Archived from the original on 5 September 2015. Retrieved 24 August 2015.
- Jones, Daniel (2003) , Peter Roach, James Hartmann and Jane Setter, eds., English Pronouncing Dictionary, Cambridge: Cambridge University Press, ISBN 978-3-12-539683-8CS1 maint: Uses editors parameter (link)
- "Stratosphere". Merriam-Webster Dictionary.
- "The Stratosphere - overview". scied.ucar.edu. University Corporation for Atmospheric Research. Retrieved 25 July 2018.
- "NWS JetStream - Layers of the Atmosphere". www.weather.gov.
- "Nasa Ozone Watch: Polar vortex facts". ozonewatch.gsfc.nasa.gov.
- Seinfeld, J. H., and S. N.(2006), Atmospheric Chemistry and Physics: From Air Pollution to Climate Change 2nd ed, Wiley, New Jersey
- "Altitude of a Commercial Jet". Hypertextbook.com. Archived from the original on 2011-10-31. Retrieved 2011-11-08.
- "Google's Alan Eustace beats Baumgartner's skydiving record". BBC News. 2014-10-24. Archived from the original on 2014-10-25.
- N.Butchart, A.A. Scaife, J. Austin, S.H.E. Hare, J.R. Knight. Quasi-biennial oscillation in ozone in a coupled chemistry-climate model Archived 2014-05-18 at the Wayback Machine, Journal of Geophysical Research.
- M.E. McIntyre, T.N. Palmer. Breaking planetary waves in the stratosphere Archived 2017-03-17 at the Wayback Machine, Nature.
- M.P. Baldwin and T.J. Dunkerton. 'Stratospheric Harbingers of Anomalous Weather Regimes Archived 2014-01-12 at the Wayback Machine, Science Magazine.
- A.A. Scaife, J.R. Knight, G.K. Vallis, C.K. Folland. A stratospheric influence on the winter NAO and North Atlantic surface climate Archived 2014-05-18 at the Wayback Machine, Geophysical Research Letters.
- DasSarma, Priya; DasSarma, Shiladitya (2018). "Survival of microbes in Earth's stratosphere". Current Opinion in Microbiology. 43: 24–30. doi:10.1016/j.mib.2017.11.002. ISSN 1369-5274. PMID 29156444.
- Michael Mark Woolfson, Time, Space, Stars & Man: The Story of the Big Bang. World Scientific; 2013. ISBN 978-1-84816-933-3. p. 388.
- Laybourne, Roxie C. (December 1974). "Collision between a Vulture and an Aircraft at an Altitude of 37,000 Feet" (PDF). The Wilson Bulletin. 86 (4): 461–462. ISSN 0043-5643. JSTOR 4160546. OCLC 46381512. Archived (PDF) from the original on 2014-02-22.
- "Audubon: Birds". Audubonmagazine.org. Archived from the original on 2011-09-14. Retrieved 2011-11-08.
- Thomas Alerstam, David A. Christie, Astrid Ulfstrand. Bird Migration (1990). Page 276.
- Steinhagen, Hans (2005), Der Wettermann - Leben und Werk Richard Aßmanns, Neuenhagen, Germany: Findling, ISBN 978-3-933603-33-3
- The dictionary definition of stratosphere at Wiktionary
- Current map of global winds and temperatures at the 10 hPa level.