Hard spheres are widely used as model particles in the statistical mechanical theory of fluids and solids. They are defined simply as impenetrable spheres that cannot overlap in space. They mimic the extremely strong ("infinitely elastic bouncing") repulsion that atoms and spherical molecules experience at very close distances. Hard spheres systems are studied by analytical means, by molecular dynamics simulations, and by the experimental study of certain colloidal model systems.

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Formal definitionEdit

Hard spheres of diameter   are particles with the following pairwise interaction potential:

 

where   and   are the positions of the two particles.

Hard-spheres gasEdit

The first three virial coefficients for hard spheres can be determined analytically

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Higher-order ones can be determined numerically using Monte Carlo integration. We list

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A table of virial coefficients for up to eight dimensions can be found on the page Hard sphere: virial coefficients.

 
Phase diagram of hard sphere system (Solid line - stable branch, dashed line - metastable branch): Pressure   as a function of the volume fraction (or packing fraction)  

The hard sphere system exhibits a fluid-solid phase transition between the volume fractions of freezing   and melting  . The pressure diverges at random close packing   for the metastable liquid branch and at close packing   for the stable solid branch.

Hard-spheres liquidEdit

The static structure factor of the hard-spheres liquid can be calculated using the Percus–Yevick approximation.

See alsoEdit

LiteratureEdit

  • J. P. Hansen and I. R. McDonald Theory of Simple Liquids Academic Press, London (1986)
  • Hard sphere model page on SklogWiki.