Decaborane, also called decaborane(14), is the borane with the chemical formula B10H14. This white crystalline compound is one of the principal boron hydride clusters, both as a reference structure and as a precursor to other boron hydrides. It is toxic and volatile, with a foul smelling odor.
3D model (JSmol)
|Molar mass||122.22 g/mol|
|Melting point||97–98 °C (207–208 °F; 370–371 K)|
|Boiling point||213 °C (415 °F; 486 K)|
|Solubility in other solvents||Slightly, in cold water. |
|Vapor pressure||0.2 mmHg|
|Main hazards||may ignite spontaneously on exposure to air|
|GHS signal word||Danger|
|H228, H301, H310, H316, H320, H330, H335, H336, H370, H372|
|P210, P240, P241, P260, P261, P262, P264, P270, P271, P280, P284, P301+310, P302+350, P304+340, P305+351+338, P307+311, P310, P312, P314, P320, P321, P322, P330, P332+313, P337+313|
|Flash point||80 °C; 176 °F; 353 K|
|149 °C (300 °F; 422 K)|
|Lethal dose or concentration (LD, LC):|
LC50 (median concentration)
|276 mg/m3 (rat, 4 hr)|
72 mg/m3 (mouse, 4 hr)
144 mg/m3 (mouse, 4 hr)
|US health exposure limits (NIOSH):|
|TWA 0.3 mg/m3 (0.05 ppm) [skin]|
|TWA 0.3 mg/m3 (0.05 ppm) ST 0.9 mg/m3 (0.15 ppm) [skin]|
IDLH (Immediate danger)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Handling properties and structureEdit
The physical characteristics of decaborane(14) resemble those of naphthalene and anthracene, all three of which are volatile colorless solids. Sublimation is the common method of purification. Decaborane is highly flammable, but, like other boron hydrides, it burns with a bright green flame. It is not sensitive to moist air, although it hydrolyzes in boiling water, releasing hydrogen and giving a solution of boric acid. It is soluble in cold water as well as a variety of non-polar and moderately polar solvents.
In decaborane, the B10 framework resembles an incomplete octadecahedron. Each boron has one "radial" hydride, and four boron atoms near the open part of the cluster feature extra hydrides. In the language of cluster chemistry, the structure is classified as "nido".
Synthesis and reactionsEdit
It is commonly synthesized via the pyrolysis of smaller boron hydride clusters. For example, pyrolysis of B2H6 or B5H9 gives decaborane, with loss of H2. On a laboratory scale, sodium borohydride is treated with boron trifluoride to give NaB11H14, which is acidified to release borane and hydrogen gas.
- B10H14 + 2 L → B10H12L2 + H2
- B10H12·2L + C2H2 → C2B10H12 + 2 L + H2
Decaborane has no significant applications, although the compound has often been investigated.
Since the molecule decomposes in a plasma, yielding monatomic boron ions, decaborane is potentially useful as a fuel for aneutronic fusion. In 2018, LPP Fusion announced plans for using the material in its next round of fusion experiments. Decaborane has been assessed for low energy ion implantation of boron in the manufacture of semiconductors. It has also been considered for plasma-assisted chemical vapor deposition for the manufacture of boron-containing thin films. In fusion research, the neutron-absorbing nature of boron has led to the use of these thin boron-rich films to "boronize" the walls of the tokamak vacuum vessel to reduce recycling of particles and impurities into the plasma and improve overall performance.
Decaborane was also developed as an additive to special high-performance rocket fuels. Its derivates were investigated as well, e.g. ethyl decaborane.
Purification by sublimation require a dynamic vacuum to remove evolved gases. Crude samples explode near 100 °C.
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